As co-first author, Yue Xin’s paper “Transition‐Metal‐Free Hydrogen Autotransfer: Diastereoselective N‐Alkylation of Amines with Racemic Alcohols” was accepted by Angew. Congratulations! Another first author is Mrs. Xiao Miao, a graduate student from Prof. Chao Wang’s group. This paper is one experimental and theoretical collaboration between Prof. Chao Wang in Shanxi Normal University, Prof. Ming Lei in Beijing University of Chemical Technology, and Prof. Jianliang Xiao in University of Liverpool supported by NSFC-RS joint project.